Prepare: Preheat oven to 350°F (177°C). Line an 8x8-inch pan with parchment paper and spray lightly with non-stick spray.
Melt: Melt butter and chopped chocolate in the microwave in 30-second intervals until smooth.
Mix Wet: Whisk in sugar, then add eggs one at a time, whisking well. Stir in vanilla.
Mix Dry: Whisk flour, cocoa powder, salt, and cornstarch in a separate bowl.
Combine: Gently mix dry ingredients into wet until just combined. Do not overmix!
Bake: Pour into pan and bake for 25-28 minutes. Edges should be set but center slightly underdone.
Cool: Cool completely in the pan on a wire rack.
Make Ganache: Pour hot simmering cream over chopped chocolate. Let sit for 2-3 mins, add corn syrup, and whisk until glossy.
Finish: Pour ganache over cooled brownies, add rainbow chips, and refrigerate for 1 hour to set.